Log into your SkyDrive account.
Copy the cid (everything after cid= and before &) from the URL
Right click Computer and select Map Network Drive
Select desired drive letter. Folder = https://d.docs.live.net/cid (change cid to your actual cid)
For specific folder
|Documents||https://d.docs.live.net/cid/^.Documents or https://d.docs.live.net/cid/^2Documents|